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An All-Solution Processed Recombination Layer with Mild Post-Treatment Enabling Efficient Homo-Tandem Non-fullerene

Shangshang Chen1,2, Guangye Zhang1,2, Jing Liu2

  • 1Hong Kong University of Science and Technology, Shenzhen Research Institute, No. 9 Yuexing 1st RD, Hi-tech Park, Nanshan, Shenzhen, 518057, P. R. China.

Advanced Materials (Deerfield Beach, Fla.)
|December 8, 2016
PubMed

Keywords:
homo-tandemmild post-treatmentorganic solar cellsrecombination layerssmall-molecular acceptors

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The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
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