Improving Surface Adsorption via Shape Control of Hematite α-Fe₂O₃ Nanoparticles for Sensitive Dopamine Sensors

α-Fe₂O₃ nanoparticles (NPs) with morphologies varying from shuttle to drum were synthesized through an anion-assisted and surfactant-free hydrothermal method by simply varying the ratios of ethanol and water in solvent. Control experiments show that the structural evolution can be attributed to a small-molecular-induced anisotropic growth mechanism in which the growth rate of α-Fe₂O₃ NPs along the a-, b-, or c-axis was well-controlled. The detailed structural analysis through the high-resolution transmission electron microscope (HRTEM) indicated that shuttle-like Fe₂O₃ NP surface was covered by high-density atomic steps, which endowed them with the enhanced adsorption and sensor ability toward dopamine (DA). The XPS characterizations indicated that the percentages of the O_C component follow the order of shuttle-like Fe₂O₃ (S-Fe₂O₃ for short) > pseudoshuttle-like Fe₂O₃ (Ps-Fe₂O₃ for short) > polyhedron-like Fe₂O₃ (Ph-Fe₂O₃ for short) > drum-like Fe₂O₃ (D-Fe₂O₃ for short). Benefits from these structural advantages, the S-Fe₂O₃ NPs-Nafion composite electrode exhibited remarkable electrochemical detection ability with a wide liner range from 0.2 μM to 0.107 mM and a low detection limit of 31.25 nM toward DA in the presence of interferents.