Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Ionic Crystal Structures02:42

Ionic Crystal Structures

19.5K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
19.5K
Electron Configuration of Multielectron Atoms03:26

Electron Configuration of Multielectron Atoms

65.9K
The alkali metal sodium (atomic number 11) has one more electron than the neon atom. This electron must go into the lowest-energy subshell available, the 3s orbital, giving a 1s22s22p63s1 configuration. The electrons occupying the outermost shell orbital(s) (highest value of n) are called valence electrons, and those occupying the inner shell orbitals are called core electrons. Since the core electron shells correspond to noble gas electron configurations, we can abbreviate electron...
65.9K
Lewis Structures of Molecular Compounds and Polyatomic Ions02:54

Lewis Structures of Molecular Compounds and Polyatomic Ions

47.4K
To draw Lewis structures for complicated molecules and molecular ions, it is helpful to follow a step-by-step procedure as outlined:
47.4K
Valence Bond Theory02:42

Valence Bond Theory

11.5K
Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
11.5K
Metallic Solids02:37

Metallic Solids

21.2K
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
21.2K
Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

52.7K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
52.7K

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

A Structurally Diverse Series of Eight-Coordinate Hg<sup>2+</sup> Complexes of KrF<sub>2</sub> Derived from Hg(PnF<sub>6</sub>)<sub>2</sub> (Pn = As, Sb) and FHg(AsF<sub>6</sub>).

Inorganic chemistry·2025
Same author

Xenon Trioxide Coordination Complexes of Crown Ethers: (CH<sub>2</sub>CH<sub>2</sub>O)<sub>4</sub>XeO<sub>3</sub> and Xe(VI) Hydrates, [(CH<sub>2</sub>CH<sub>2</sub>O)<sub>6</sub>(H<sub>2</sub>O)XeO<sub>3</sub>]⋅ H<sub>2</sub>O and [(CH<sub>2</sub>CH<sub>2</sub>O)<sub>6</sub>(H<sub>2</sub>O)XeO<sub>3</sub>]<sub>2</sub> ⋅ 2H<sub>2</sub>O ⋅ HF.

Angewandte Chemie (International ed. in English)·2025
Same author

Hydroaminoalkylation for Amine Functionalization of Vinyl-Terminated Polyethylene Enables Direct Access to Responsive Functional Materials.

Angewandte Chemie (International ed. in English)·2024
Same author

Chromium(VI) Oxyfluoride Dianions, [Cr<sub>2</sub> O<sub>4</sub> F<sub>6</sub> ]<sup>2-</sup> and [CrO<sub>2</sub> F<sub>4</sub> ]<sup>2-</sup> ; Syntheses and Structures of [XeF<sub>5</sub> ]<sub>2</sub> [Cr<sub>2</sub> O<sub>4</sub> F<sub>6</sub> ], [XeF<sub>5</sub> ]<sub>2</sub> [Cr<sub>2</sub> O<sub>4</sub> F<sub>6</sub> ] ⋅ nX (X=HF, n=4; X=XeOF<sub>4</sub> , n=2), and [XeF<sub>5</sub> ][Xe<sub>2</sub> F<sub>11</sub> ][CrO<sub>2</sub> F<sub>4</sub> ].

Chemistry (Weinheim an der Bergstrasse, Germany)·2023
Same author

XeF<sub>2</sub> Coordination Complexes of the [BrO<sub>2</sub>]<sup>+</sup> Cation, [O<sub>2</sub>Br(FXeF)<sub></sub>][AsF<sub>6</sub>] (<i>n</i> = 1, 2) and [O<sub>2</sub>Br(FXeF)<sub>2</sub>][SbF<sub>6</sub>]; Their Syntheses and Structural Characterizations.

Inorganic chemistry·2023
Same author

Synthesis, Structure, and Bonding of a Xe<sup>IV</sup> Transition-Metal Coordination Complex, F<sub>3</sub> XeF<sub>b</sub> - - -WOF<sub>4</sub>.

Angewandte Chemie (International ed. in English)·2022

Related Experiment Video

Updated: Mar 10, 2026

Growth and Electrostatic/chemical Properties of Metal/LaAlO3/SrTiO3 Heterostructures
11:54

Growth and Electrostatic/chemical Properties of Metal/LaAlO3/SrTiO3 Heterostructures

Published on: February 8, 2018

10.8K

Solid-State Structures of XeO3.

James T Goettel1, Gary J Schrobilgen1

  • 1Department of Chemistry, McMaster University , Hamilton, Ontario L8S 4M1, Canada.

Inorganic Chemistry
|December 20, 2016
PubMed
Summary

Xenon trioxide (XeO3) exhibits polymorphism, with three distinct solid-state structures (α, β, and γ phases) identified. These phases arise from varying crystallization conditions and Xe═O---Xe interactions, influencing their density and structural properties.

Area of Science:

  • Solid-state chemistry
  • Inorganic chemistry
  • Crystallography

Background:

  • Xenon trioxide (XeO3) is a compound with known solid-state structures.
  • Understanding its structural polymorphism is crucial for predicting its chemical behavior.

Purpose of the Study:

  • To reinvestigate the solid-state structure of xenon trioxide (XeO3).
  • To identify and characterize different polymorphic phases of XeO3.
  • To elucidate the factors governing XeO3 polymorphism.

Main Methods:

  • Low-temperature single-crystal X-ray diffraction.
  • Crystallization under varying conditions (evaporation of aqueous HF solutions vs. aqueous solutions).
  • Ambient-temperature Raman spectroscopy.

More Related Videos

Tuning Oxide Properties by Oxygen Vacancy Control During Growth and Annealing
06:44

Tuning Oxide Properties by Oxygen Vacancy Control During Growth and Annealing

Published on: June 9, 2023

3.9K
Elemental-sensitive Detection of the Chemistry in Batteries through Soft X-ray Absorption Spectroscopy and Resonant Inelastic X-ray Scattering
07:55

Elemental-sensitive Detection of the Chemistry in Batteries through Soft X-ray Absorption Spectroscopy and Resonant Inelastic X-ray Scattering

Published on: April 17, 2018

13.3K

Related Experiment Videos

Last Updated: Mar 10, 2026

Growth and Electrostatic/chemical Properties of Metal/LaAlO3/SrTiO3 Heterostructures
11:54

Growth and Electrostatic/chemical Properties of Metal/LaAlO3/SrTiO3 Heterostructures

Published on: February 8, 2018

10.8K
Tuning Oxide Properties by Oxygen Vacancy Control During Growth and Annealing
06:44

Tuning Oxide Properties by Oxygen Vacancy Control During Growth and Annealing

Published on: June 9, 2023

3.9K
Elemental-sensitive Detection of the Chemistry in Batteries through Soft X-ray Absorption Spectroscopy and Resonant Inelastic X-ray Scattering
07:55

Elemental-sensitive Detection of the Chemistry in Batteries through Soft X-ray Absorption Spectroscopy and Resonant Inelastic X-ray Scattering

Published on: April 17, 2018

13.3K

Main Results:

  • Three polymorphic phases of XeO3 were identified: α (orthorhombic), β (rhombohedral), and γ (rhombohedral).
  • The α-phase forms from HF solutions, while β and γ phases form from aqueous solutions.
  • Extended structures are stabilized by Xe═O---Xe bridge interactions, linked to XeO3's amphoteric nature.
  • The α-phase is denser and shows greater variation in contact distances compared to the rhombohedral phases.
  • Raman spectra for α- and γ-XeO3 were obtained and assigned.

Conclusions:

  • Xenon trioxide (XeO3) exhibits condition-dependent polymorphism.
  • The amphoteric nature of XeO3 drives the formation of secondary bonding interactions in its solid-state structures.
  • Structural differences impact density and bonding characteristics across the identified phases.