Dithienobenzodithiophene-Based Small Molecule Organic Solar Cells with over 7% Efficiency via Additive- and
Hyeng Gun Song, Yu Jin Kim1, Ji Sang Lee
1POSTECH Organic Electronics Laboratory, Department of Chemical Engineering, Pohang University of Science and Technology , Pohang 790-784, Republic of Korea.
Abstract:
Here we introduce a novel small molecule based on dithienobenzodithiophene and rhodanine, DTBDT-Rho, developed to study the effect of the rhodanine substitutuent on small molecule bulk heterojunction (BHJ) solar cells. DTBDT-Rho possesses distinct crystalline characteristics, sufficient solubility in chlorinated solvents, and broad absorption properties. Therefore, solution-processed BHJ photovoltaic cells made with DTBDT-Rho:PC71BM blends showed an extremely high power conversion efficiency (PCE; 7.10%); notably, this PCE value was obtained without the use of additives or thermal treatments. To our knowledge, the PCE over 7% is a significantly powerful value among rhodanine-based small molecule BHJ solar cells without additives or thermal treatments.
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