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Updated: Mar 9, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
A five-fold interpenetrated metal-organic framework showing a large variation in thermal expansion behaviour owing to
Himanshu Aggarwal1, Raj Kumar Das1, Emile R Engel1
1Department of Chemistry and Polymer Science, University of Stellenbosch, Matieland 7602, Stellenbosch, South Africa. ljb@sun.ac.za.
Abstract:
A five-fold interpenetrated metal organic framework (MOF) has been shown to exhibit anomalous thermal expansion due to the combined effect of hinge-like motion and sliding of individual diamondoid networks. Upon dehydration, the MOF undergoes dramatic structural changes, thereby altering its thermal expansion behaviour to a large extent.
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