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Quantum Tunneling: The Longer the Path, the Less Time it Takes.
1Chemical Physics Department, Weizmann Institute of Science , 76100 Rehovoth, Israel.
The Journal of Physical Chemistry Letters
|December 31, 2016
Summary
Quantum tunneling times are redefined using positive time correlation functions. Lowering temperature enhances tunneling, shifting transition times shorter and decreasing mean transit time with path length, even with friction.
Area of Science:
- Quantum mechanics
- Quantum dynamics
- Statistical mechanics
Background:
- Standard tunneling time calculations lack a rigorous quantum mechanical foundation.
- Time correlation functions offer a novel approach to quantum dynamics.
Purpose of the Study:
- To develop a new formalism for quantum mechanical transition times using correlation functions.
- To investigate quantum dynamics and transition time distributions for a parabolic barrier.
Main Methods:
- Utilizing a class of always-positive correlation functions.
- Defining quantum mechanical transition time probability distributions.
- Analyzing a thermal position correlation function for a parabolic barrier Hamiltonian.
Main Results:
- Transition time probability distributions shift to shorter times with reduced temperature and increased tunneling.
- Mean transition time decreases with increasing path length at low temperatures where tunneling dominates.
- Friction's effect on this phenomenon is minimal unless the friction coefficient is very large.
Conclusions:
- The developed correlation function formalism provides a robust method for studying quantum tunneling times.
- Temperature and friction significantly influence quantum transition dynamics.
- The findings offer new insights into the nature of time in quantum mechanics.
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