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Reductive Electropolymerization of a Vinyl-containing Poly-pyridyl Complex on Glassy Carbon and Fluorine-doped Tin Oxide Electrodes
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Why Are Vinyl Cations Sluggish Electrophiles?

Peter A Byrne1, Shinjiro Kobayashi1, Ernst-Ulrich Würthwein2

  • 1Department Chemie, Ludwig-Maximilians-Universität München , Butenandtstrasse 5-13, 81377 München, Germany.

Journal of the American Chemical Society
|January 3, 2017
PubMed
Summary

Vinyl cations exhibit unique reactivity with nucleophiles, differing significantly from benzhydrylium ions due to high intrinsic barriers in their formation and reactions. This impacts their overall reaction rates and stability.

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