Variability in the backscattering efficiency of particles in the Bohai and Yellow Seas and related effects on optical...

The backscattering efficiency of particles is a crucial factor that relates light backscattering with biogeochemical properties. In this study, based on in situ measurements of the backscattering coefficient (b_bp(λ)), particle biogeochemical variables and remote sensing reflectance (R_rs(λ)) in two typical shallow and semi-enclosed seas, namely the Bohai Sea (BS) and Yellow Sea (YS) during the late spring, late summer and late autumn, we examined particulate pseudo-backscattering efficiency variability at 640 nm (P_Q_bbe(640)) and related optical effects. The results show that the P_Q_bbe(640) levels varied by nearly two orders for all of the samples examined. This high degree of P_Q_bbe(640) variability significantly affected b_bp(640) and the mass-specific backscattering coefficient (b_bp*(640)), showing that approximately 63.7% and 20.8% of the variability in the b_bp*(640) and b_bp(640) was attributed to the P_Q_bbe(640), respectively. More importantly, consistent with the observations of Wang et al. [J. Geophys. Res.: Oceans 121, 3955 (2016)], the P_Q_bbe(640) results clearly showed two clusters and this clustering changed the relationships between b_bp*(640), b_bp(640) and R_rs(640) with the biogeochemical variables. However, we confirm that P_Q_bbe(640) clustering generally remained intact across seasons. Therefore, a simple scheme based on a threshold of the P_Q_bbe(640) data is proposed for the classification of particle types. With this classification, impacts of P_Q_bbe(640) on b_bp*(640) and b_bp(640) were clearly reduced, and co-variation trends of b_bp*(640), b_bp(640) and R_rs(640) with biogeochemical variables can be in turn more accurately described. Overall, this study provides general information on P_Q_bbe(640) variability in the BS and the YS and consequent effects on optical properties. The scheme for particle type classification may also provide a useful basis for better modeling marine biogeochemical processes related to particulate backscattering and for the development of ocean color algorithms.