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Synthesis of Mono-, Di-, and Trinuclear Rhodium Diphosphine Complexes Containing Light-Harvesting Fluorene Backbones
Yuko Matsusaka1, Shoji Shitaya1, Kotohiro Nomura1
1Graduate School of Science and Engineering, Tokyo Metropolitan University . 1-1 Minami-Osawa, Hachioji, Tokyo 192-0397, Japan.
Inorganic Chemistry
|January 7, 2017
Abstract:
Syntheses and structural determination of rhodium complexes ligated by diphosphines containing light-harvesting fluorene backbones are presented. In these rhodium complexes, the rhodium center is surrounded by a light-absorbing diphosphine unit. The presence of Rh-Rh bonding interactions is suggested by density functional theory studies.

