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Sensitizers for Aqueous-Based Solar Cells.

Chun-Ting Li1, Ryan Yeh-Yung Lin2, Jiann T Lin1

  • 1Institute of Chemistry, Academia Sinica, Nankang, Taipei, 11529, Taiwan.

Chemistry, an Asian Journal
|January 11, 2017
PubMed
Summary

Aqueous dye-sensitized solar cells (DSSCs) offer sustainable energy solutions. Research addresses dye leaching and wettability challenges to improve performance and enable water splitting applications.

Keywords:
anchorsquantum dotssensitizerssolar cellssurface chemistrywettability

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Area of Science:

  • Materials Science
  • Renewable Energy
  • Electrochemistry

Background:

  • Aqueous dye-sensitized solar cells (DSSCs) are explored for sustainability and water splitting.
  • Key challenges include dye leaching and poor dye wettability in aqueous electrolytes.
  • Quantum-dot-sensitized solar cells (QDSSCs) are also considered for enhanced performance.

Purpose of the Study:

  • To review strategies for overcoming dye leaching and wettability issues in aqueous DSSCs.
  • To discuss advancements in sensitizers, redox mediators, and photoanode treatments.
  • To highlight improvements in QD loading and charge recombination in QDSSCs.

Main Methods:

  • Modification of dye molecular skeletons and anchoring groups.
  • Incorporation of hydrophilic entities or surfactants for improved wettability.
  • Surface treatments of photoanodes and optimization of redox mediators.
  • Enhancements in quantum dot loading and interfacial charge recombination suppression.

Main Results:

  • Molecular modifications enhance dye stability against leaching.
  • Hydrophilic modifications and surfactants improve dye wettability and regeneration.
  • Photoanode surface treatments mitigate dye leaching and enhance wettability.
  • Optimized redox mediators and QD strategies improve cell efficiency.

Conclusions:

  • Addressing dye leaching and wettability is crucial for aqueous DSSC advancement.
  • Tailored sensitizers, electrolytes, and photoanodes are key to high-performance aqueous DSSCs.
  • Further research in QDSSCs can lead to significant improvements in solar energy conversion.