Environmental Beneficiation of Machining Wastes-Part III: Effects of Metal Working Fluids on the Spontaneous Heating...

Machining swarf is a finely divided metal powder that is prone to spontaneous heating and, in some cases, spontaneous combustion. The fine particle size, large amount of particle surface area, and the presence of moisture all promote rapid oxidation. This hazard dramatically increases disposal costs for swarf and interferes with recycling efforts. A potential method for minimizing spontaneous heating and facilitating recycling of the swarf is to spray a fluid on the material that coats the particles and creates a barrier between the metal and oxygen. Surface coatings could be tested for their effects on the spontaneous heating potential of swarf by treating a sample of swarf with a fluid that would coat the particles, then monitoring its heating behavior. This paper describes the results of applying corrosion inhibitors and machining fluids to the swarf, and monitoring the spontaneous heating behavior using a testing method developed specifically for this purpose. The effects of different types of surfactants and the effects of surfactant concentration on the spontaneous heating of swarf are discussed.