New Wide Band Gap Donor for Efficient Fullerene-Free All-Small-Molecule Organic Solar Cells
Liyan Yang1,2, Shaoqing Zhang1,3, Chang He1,2
1Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences , Beijing 100190, China.
Abstract:
A new organic small molecule, DRTB-T, that incorporates a two-dimensional trialkylthienyl-substituted benzodithiophene core building block was designed and synthesized. DRTB-T has a band gap (Egopt) of 2.0 eV with a low-lying highest occupied molecular orbital (HOMO) level of -5.51 eV. Nonfullerene small-molecule solar cells consisting of DRTB-T and a nonfullerene acceptor (IC-C6IDT-IC) were constructed, and the morphology of the active layer was fine-tuned by solvent vapor annealing (SVA). The device showed a record 9.08% power conversion efficiency (PCE) with a high open-circuit voltage (Voc = 0.98 V). This is the highest PCE for a nonfullerene small-molecule organic solar cell (NFSM-OSC) reported to date. Our notable results demonstrate that the molecular design of a wide band gap (WBG) donor to create a well-matched donor-acceptor pair with a low band gap (LBG) nonfullerene small-molecule acceptor, as well as subtle morphological control, provides great potential to realize high-performance NFSM-OSCs.
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