27Al-27Al double-quantum single-quantum MAS NMR: Applications to the structural characterization of microporous
Charlotte Martineau-Corcos1, Jiri Dědeček2, Francis Taulelle3
1Institut Lavoisier de Versailles, CNRS UMR 8180, Université de Versailles Saint-Quentin en Yvelines, 45 Avenue des Etats-Unis, Versailles Cedex 78035, France; CNRS, CEMHTI UPR3079, Université d'Orléans, Orléans F-45071, France.
Abstract:
In this paper, we review and illustrate applications, reported in the literature or used in our group, of 27Al-27Al double-quantum single-quantum (DQ-SQ) MAS NMR experiments for the structural characterization of Al-containing microporous solids, namely zeolites, aluminophosphates and metal-organic frameworks. Information regarding the periodic frameworks or the localization of the various aluminum species in the materials are obtained from the analysis of the two-dimensional NMR spectra, which allows getting local structural details sometimes inaccessible from other characterization technique. An application of 27Al-27Al of the DQ-SQ experiment for the detection of aluminum pairing in zeolite is shown.
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