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Fast-Initiating, Ruthenium-based Catalysts for Improved Activity in Highly E-Selective Cross Metathesis

Tonia S Ahmed1, Robert H Grubbs1

  • 1The Arnold and Mabel Beckman Laboratory of Chemical Synthesis, Division of Chemistry and Chemical Engineering. California Institute of Technology , Pasadena, California 91125, United States.

Journal of the American Chemical Society
|January 21, 2017
PubMed
Summary

Ruthenium catalysts for olefin synthesis achieve high E-selectivity but low yields. A new ligand design significantly improves initiation rates, leading to faster reactions and higher yields while maintaining excellent stereoselectivity.

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