Imbibition Triggered by Capillary Condensation in Nanopores

We study the spatiotemporal dynamics of water uptake by capillary condensation from unsaturated vapor in mesoporous silicon layers (pore radius r_p ≃ 2 nm), taking advantage of the local changes in optical reflectance as a function of water saturation. Our experiments elucidate two qualitatively different regimes as a function of the imposed external vapor pressure: at low vapor pressures, equilibration occurs via a diffusion-like process; at high vapor pressures, an imbibition-like wetting front results in fast equilibration toward a fully saturated sample. We show that the imbibition dynamics can be described by a modified Lucas-Washburn equation that takes into account the liquid stresses implied by Kelvin equation.