Facile Face-Down Annealing Triggered Remarkable Texture Development in CH₃NH₃PbI₃ Films for High-Performance...

Herein, we demonstrate that the facile face-down annealing route which effectively confines the evaporation of residual solvent molecules in one-step deposited precursor films can controllably enable the formation of (110) textured CH₃NH₃PbI₃ films consisting of high-crystallinity well-ordered micrometer-sized grains that span vertically the entire film thickness. Such microstructural features dramatically decrease nonradiative recombination sites as well as greatly improve the transport property of charge carries in the films compared with that of the nontextured ones obtained by the conventional annealing route. As a consequence, the planar-heterojunction perovskite solar cells with these textured CH₃NH₃PbI₃ films exhibit significantly enhanced power conversion efficiency (PCE) along with small hysteresis and excellent stability. The champion cell yields impressive PCE boosting to 18.64% and a stabilized value of around 17.22%. Particularly, it can maintain 86% of its initial value after storage for 20 days in ambient conditions with relative humidity of 10-20%. Our work suggests a facile and effective route for further boosting the efficiency and stability of low-cost perovskite solar cells.