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Updated: Mar 8, 2026

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
Individual (f,t A)- and (f,t C)-Fullerene-Based Nickel(II) Glycinates: Protected Chiral Amino Acids Directly Linked
Oleg A Levitskiy1, Yuri K Grishin1, Olesya O Semivrazhskaya1
1Chemistry Department, Lomonosov Moscow State University, Leninskie Gory 1/3, Moscow, Russia.
Abstract:
Stereoselective electrosynthesis of the first individual (f,t A)- and (f,t C)-1,4-fullerene derivatives with a non-inherently chiral functionalization pattern is described, as well as the first example of an optically pure protected primary amino acid directly linked to the fullerene through only the chiral α-amino-acid carbon atom. An application of an auxiliary chiral nickel-Schiff base moiety as derivatizing agent allowed separation of (f,t A)- and (f,t C)-1,4-fullerene derivatives using an achiral stationary phase, a separation which has never been done before.
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