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FTIR spectroscopic study of the complex formation between H+ and DMSO in Nafion

A I Karelin1, R R Kayumov1, E A Sanginov1

  • 1Institute of Problems of Chemical Physics of RAS, 142432, 1 Academician Semenov avenue, Chernogolovka, Moscow region, Russia.

Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy
|February 8, 2017
PubMed

Keywords:
ATR - FTIR spectroscopyComplexes H(+)(DMSO)(2) and H(+)(DMSO-d(6))(2)DMSO plasticizationDipole-dipole interactionsIon pair SO(3)(−)H(+)(DMSO)(2)Isotope substitution H(+)D(+)Nafion membraneProtonic conductivityStrong hydrogen bond OH(+)OSymmetry decrease

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