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Related Experiment Video

Updated: Mar 7, 2026

Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
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Intermediate Temperature Brittleness in Metallic Glasses.

Chao Wang1, Qing Ping Cao1, Xiao Dong Wang1

  • 1International Center for New-Structured Materials (ICNSM), Zhejiang University and Laboratory of New-Structured Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027, P. R. China.

Advanced Materials (Deerfield Beach, Fla.)
|February 10, 2017
PubMed
Summary

Metallic glasses (MGs) exhibit unexpected brittleness at intermediate temperatures (0.6-0.7 Tg). This phenomenon, unlike typical material behavior, is linked to competing shear banding and diffusive relaxation processes.

Keywords:
ductilitymetallic glassshear bands

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Area of Science:

  • Materials Science
  • Condensed Matter Physics

Background:

  • Metallic glasses (MGs) generally exhibit enhanced ductility with increasing temperature.
  • However, a peculiar brittle behavior is observed in MGs within a specific temperature range.

Purpose of the Study:

  • To explain the underlying mechanisms behind the brittle behavior of metallic glasses at intermediate temperatures.
  • To investigate the competition between shear banding and diffusive relaxation in metallic glasses.

Main Methods:

  • Analysis of deformation mechanisms in metallic glasses.
  • Comparison with phenomena observed in polycrystalline metals.

Main Results:

  • All metallic glasses (MGs) demonstrate brittle behavior between 0.6-0.7 Tg, irrespective of composition.
  • This contrasts with the expected increase in strain tolerance with rising temperatures.

Conclusions:

  • The observed brittleness in MGs is attributed to the interplay between shear banding and diffusive relaxation.
  • This behavior is analogous to the 'intermediate temperature ductility minimum' seen in polycrystalline metals.