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Elucidating light-induced charge accumulation in an artificial analogue of methane monooxygenase enzymes using
Dooshaye Moonshiram1, Antonio Picón1, Alvaro Vazquez-Mayagoitia2
1Chemical Sciences and Engineering Division, 9700 S. Cass Avenue, Lemont IL 60439, USA. dmoonshi@gmail.com.
Chemical Communications (Cambridge, England)
|February 16, 2017
Abstract:
We report the use of time-resolved X-ray absorption spectroscopy in the ns-μs time scale to track the light induced two electron transfer processes in a multi-component photocatalytic system, consisting of [Ru(bpy)3]2+/ a diiron(iii,iii) model/triethylamine. EXAFS analysis with DFT calculations confirms the structural configurations of the diiron(iii,iii) and reduced diiron(ii,ii) states.
