Azobenzene-based ruthenium(ii) catalysts for light-controlled hydrogen generation.

A Telleria1, P W N M van Leeuwen2, Z Freixa3

  • 1Department of Applied Chemistry, Faculty of Chemistry, University of the Basque Country (UPV-EHU), 20080 San Sebastián, Spain. Zoraida_freixa@ehu.eus.

Summary

New ruthenium(II) complexes with azobenzene ligands were synthesized. Some complexes enable light-controlled hydrogen generation from ammonia-borane (AB) decomposition, demonstrating photo-switchable catalysis.

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