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Emulsions stabilized by high acyl gellan and KCl
Joice Aline Pires Vilela1, Rosiane Lopes da Cunha1
1Department of Food Engineering, School of Food Engineering, University of Campinas (UNICAMP), 13083-862 Campinas, SP, Brazil.
High acyl gellan gum effectively stabilizes emulsions, but properties like viscosity and droplet size are modulated by potassium chloride (KCl) concentration. Optimal KCl levels enhance stability, while excessive salt causes emulsion breakdown.
Area of Science:
- Food science and technology
- Colloid and surface chemistry
Background:
- Gellan gum is a polysaccharide used as a stabilizer in food products.
- Emulsion stability is crucial for product quality and shelf-life.
Purpose of the Study:
- To investigate the effect of potassium chloride (KCl) concentration on high acyl gellan gum stabilized emulsions.
- To determine the optimal salt-polysaccharide ratio for emulsion stability.
Main Methods:
- Emulsions were prepared using high acyl gellan gum (0.025% or 0.100% w/w) and varying KCl concentrations (1.6–15,633 mg/g gellan).
- Apparent viscosity and droplet size were measured.
- Macroscopic phase separation was assessed to evaluate emulsion stability.
Main Results:
- Increasing KCl concentration generally decreased apparent viscosity and increased droplet size.
- Intermediate KCl levels (62.6–1,563 mg/g gellan) improved emulsion stability for 0.025% gellan.
- High KCl concentrations (>1,563 mg/g gellan) led to emulsion breakdown.
Conclusions:
- Emulsion properties are tunable via the salt-polysaccharide ratio, enabling tailored emulsions for specific applications.
- Stabilization mechanisms include high continuous phase viscosity and droplet repulsion.
- Gellan aggregate deposition at droplet interfaces may occur under specific KCl-gellan ratios.
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