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Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers
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Monomer design strategies to create natural product-based polymer materials
Samantha L Kristufek1, Kevin T Wacker1, Yi-Yun Timothy Tsao1
1Department of Chemistry, Department of Chemical Engineering, Department of Materials Science & Engineering, Texas A&M University, College Station, Texas 77842-3012, USA. wooley@chem.tamu.edu.
Natural Product Reports
|March 15, 2017
Summary
Synthetic organic chemistry enhances bio-based polymers from natural products like oils, terpenes, lignin, and sugars. This review explores novel monomers derived from these sustainable resources.
Area of Science:
- Polymer Chemistry
- Organic Chemistry
- Materials Science
Background:
- Natural products are increasingly explored for sustainable polymer development.
- Bridging synthetic organic and polymer chemistry offers novel material design possibilities.
- Bio-based polymers aim to enhance material function and environmental sustainability.
Purpose of the Study:
- To review the integration of synthetic organic chemistry with natural products for novel polymer synthesis.
- To explore the preparation of monomers from various bio-based feedstocks.
- To highlight advancements in creating functional and sustainable synthetic polymers.
Main Methods:
- Utilizing synthetic organic transformations (e.g., functional group interconversion, protection/deprotection).
- Designing and preparing monomers from natural product classifications.
- Reviewing literature on synthetic bio-based polymer systems from 2010 to August 2016.
Main Results:
- Demonstrated successful synthetic modifications of natural products into polymerizable monomers.
- Showcased diverse natural product sources including oils, fatty acids, terpenes, lignin, and sugars.
- Detailed various synthetic strategies for creating novel bio-based polymer structures.
Conclusions:
- Synthetic organic chemistry is a powerful tool for unlocking the potential of natural products in polymer science.
- The described methods enable the creation of novel, functional, and sustainable bio-based polymers.
- This approach contributes to the growing field of green chemistry and sustainable materials.
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