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Updated: Mar 6, 2026

Low-energy Cathodoluminescence for OxyNitride Phosphors
Published on: November 15, 2016
Optical spectroscopy, 1.06μm emission properties of Nd3+-doped phosphate based glasses
Rasool Sk Nayab1, Sasikala T2, Mohan Babu A3
1Department of Material Science and Engineering, Shenzhen Graduate School, Harbin Institute of Technology, Shenzhen 518055, China; Department of Physics, Rajeev Gandhi Memorial College of Engineering and Technology, Nandyal 518501, Andhra Pradesh, India.
Abstract:
Neodymium doped phosphate based glasses with composition of (P2O5+K2O+Al2O3+CaF2) were prepared. The samples were analysed through differential thermal analysis (DTA), Fourier transform infrared (FTIR), absorption, emission and decay measurements. Judd-Ofelt parameters (Ωλ) have been determined from the spectral intensities of absorption bands in order to calculate the radiative parameters like radiative transition probabilities (AR), radiative lifetime (τR) and branching ratios (βR) for the 4F3/2→4I11/2 laser transition of Nd3+ ion. The effective emission bandwidths (Δλeff), experimental branching ratios (βexp) and stimulated emission cross-sections (σe) have been determined from the emission spectrum. The decay curves of the 4F3/2 level exhibited almost single exponential nature for all the Nd3+ ion concentrations.
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