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Updated: Mar 6, 2026
Preparation of Polyoxometalate-based Photo-responsive Membranes for the Photo-activation of Manganese Oxide Catalysts
Published on: August 7, 2018
A novel naphthalenediimide-based lanthanide-organic framework with polyoxometalate templates exhibiting reversible
Hai-Long Zhang1, Jian-Zhen Liao, Wenbin Yang
1Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. czlu@fjirsm.ac.cn.
Abstract:
The first visible-light-responsive photochromic polyoxometalate-templated lanthanide-organic framework (LOF) has been constructed from a carboxyphenyl-substituted naphthalenediimide (NDI) derivative, which displays an unusual four-fold interpenetration of an srs topological network, featuring a variety of anion-π interactions between polyoxoanions and π-acidic NDI moieties, and undergoes a rapid reversible photochromic transformation upon blue light irradiation.
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