Evidence of a minority monoclinic LaNiO_2.5 phase in lanthanum nickelate thin films

LaNiO₃ (LNO) thin films of 14 nm and 35 nm thicknesses grown epitaxially on LaAlO₃ (LAO) and (LaAlO₃)_0.3(Sr₂TaAlO₆)_0.7 (LSAT) substrates are studied using High Resolution Transmission Electron Microscopy (HRTEM) and High Angle Annular Dark Field (HAADF) imaging. The strain state of the films is studied using Geometric Phase Analysis (GPA). Results show the successful in-plane adaptation of the films to the substrates, both in the compressive (LAO) and tensile (LSAT) cases. Through the systematic analysis of HRTEM superstructure contrast modulation along different crystal orientations, localized regions of the monoclinic LaNiO_2.5 phase are detected in the 35 nm films.