Metal-Organic Framework UiO-66 Layer: A Highly Oriented Membrane with Good Selectivity and Hydrogen Permeance

The 3D metal-organic framework (MOF) structure UiO-66 [Zr₆O₄(OH)₄(bdc)₆], featuring triangular pores of approximately 6 Å, has been successfully prepared as a thin supported membrane layer with high crystallographic orientation on ceramic α-Al₂O₃ supports. The adhesion of the MOF layer to the ceramic support was investigated in different taxing conditions. Furthermore, by coating this UiO-66 membrane with a thin polyimide (Matrimid) top layer, we prepared a multilayer composite. Said membranes have been evaluated in the separation of hydrogen (H₂) from different binary mixtures at room temperature. H₂ as the smallest molecule (2.9 Å) should pass the UiO-66 membrane preferably since the kinetic diameters of all the other gases under study are larger. The gas mixture separation factors for the neat UiO-66 membrane were indeed found to be H₂/CO₂ = 5.1, H₂/N₂ = 4.7, H₂/CH₄ = 12.9, H₂/C₂H₆ = 22.4, and H₂/C₃H₈ = 28.5. The coating with Matrimid led to a sharp cutoff for gases with kinetic diameters greater than 3.7 Å, resulting in increased separation performance.