Mesoporous magnesium oxide nanoparticles derived via complexation-combustion for enhanced performance in carbon...

Magnesium oxide (MgO) is a promising candidate for carbon dioxide (CO₂) capture at high temperature applicable to pre-combustion capture in an integrated gasification combined cycle (IGCC) scheme. In this work, mesoporous MgO nanoparticles were synthesized via simple complexation-combustion method by using glycine (G) and urea (U) as fuels (F). The obtained sorbents were thoroughly characterized in terms of the crystalline structure, morphology, nature of the fuel, F/O ratio, and their consequent effects on CO₂ sorption. It was observed that due to the complexation followed by combustion in the presence of glycine, MgO with crystallite size as small as∼8nm could be derived. The synthesized MgO nanoparticles exhibited exceptionally high CO₂ sorption at elevated temperatures. Furthermore, CO₂ sorption isotherms in assistance with FT-IR and DSC experiments demonstrated that the low CO₂ uptake at ambient temperature (25-100°C) may be due to the formation of monodentate carbonates, whereas predominant bicarbonates enhance the CO₂ uptake at elevated temperatures (100-300°C). MgO-1.5(G) obtained the highest sorption corresponding to 1.34mmol/g at 200°C.