Spontaneous wormlike micelles formed in a single-tailed zwitterionic surface-active ionic liquid aqueous solution

Wormlike micelles were successfully fabricated by the self-assembly of a single-tailed zwitterionic surface-active ionic liquid (SAIL), 3-(1-hexadecyl-3-imidazolio) propanesulfonate β-naphthalene sulfonate (C₁₆IPS-Nsa), in aqueous solutions without any additives. With increasing zwitterionic SAIL concentration, spontaneous transition from micelles to wormlike micelles and then a hexagonal phase occurs. Interestingly, the wormlike micelles are closed, stretched and directionally arranged, which was rarely found in previous research studies. This kind of wormlike micelle is useful to serve as novel soft template in the synthesis of functional materials. ¹H NMR illustrated that the introduced π-π stacking and hydrophobic interactions originated from the hydrophobic aromatic counterions are responsible for the structural transformation. Density functional theory (DFT) simulated the optimum configuration of C₁₆IPS-Nsa and calculated the interaction energy of C₁₆IPS-Nsa-H₂O is 39.6 kJ mol^-1. This work paves the way for regulating the self-assembly structures of amphiphiles through changing specific weak interactions.