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Updated: Mar 5, 2026
Fabrication of Amperometric Electrodes
Published on: May 4, 2009
Hierarchical meso/macro-porous carbon fabricated from dual MgO templates for direct electron transfer enzymatic
Hiroto Funabashi1, Satoshi Takeuchi1, Seiya Tsujimura1
1Division of Materials Science, Faculty of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8573, Japan.
Abstract:
We designed a three-dimensional (3D) hierarchical pore structure to improve the current production efficiency and stability of direct electron transfer-type biocathodes. The 3D hierarchical electrode structure was fabricated using a MgO-templated porous carbon framework produced from two MgO templates with sizes of 40 and 150 nm. The results revealed that the optimal pore composition for a bilirubin oxidase-catalysed oxygen reduction cathode was a mixture of 33% macropores and 67% mesopores (MgOC33). The macropores improve mass transfer inside the carbon material, and the mesopores improve the electron transfer efficiency of the enzyme by surrounding the enzyme with carbon.
