Probing polarity of flame retardants and correlating with interaction between flame retardants and PET fiber

The empirical polarity parameter E_T(30) was determined for polyethylene terephthalate (PET) fiber and five phosphorus flame retardants by UV-Vis absorption spectrum of solvatochromic probe. To investigate the interaction between flame retardant and PET fiber during the finishing process, the partition coefficients K of these flame retardants between water and PET fiber were determined and an interesting linear relationship between lnK and E_T(30) of the flame retardants was obtained, suggesting E_T(30) is definitely an excellent estimation of the interaction of flame retardants with PET. Additionally, the thermodynamic criterion of this finishing process, standard Gibbs free energy of transfer of the flame retardants from water to PET fiber, ΔG_t⁰(FR,H₂O→PET), was found to linearly correlate with E_T(30) of the flame retardants as well, ΔG_t⁰(FR,H₂O→PET)=0.3664∗E_T(30)(FR) -18.60 (R²=0.9168), demonstrating polarity of flame retardant is an important and determining factor for its fixation on PET fiber. This work may provide theoretical guidance for choosing flame retardant finishing agent more compatible with PET fabric.