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Published on: November 9, 2015
Surface Wettability Modification of Cyclic Olefin Polymer by Direct Femtosecond Laser Irradiation
Bing Wang1,2, Xincai Wang3,4, Hongyu Zheng5,6
1SIMTech-NTU Joint Laboratory (Precision Machining), Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore. wangbing@ntu.edu.sg.
Abstract:
The effect of laser irradiation on surface wettability of cyclic olefin polymer (COP) was investigated. Under different laser parameters, a superhydrophilic or a superhydrophobic COP surface with a water contact angle (WCA) of almost 0° or 163°, respectively, could be achieved by direct femtosecond laser irradiation. The laser power deposition rate (PDR) was found to be a key factor on the wettability of the laser-treated COP surface. The surface roughness and surface chemistry of the laser-irradiated samples were characterized by surface profilometer and X-ray photoelectron spectroscopy, respectively; they were found to be responsible for the changes of the laser-induced surface wettability. The mechanisms involved in the laser surface wettability modification process were discussed.

