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Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
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Self-assembly of gradient copolymers synthesized in semi-batch mode by nitroxide mediated polymerization

Kevin Wylie1, Ian Bennett, Milan Marić

  • 1Dept. of Chemical Engineering, McGill Institute of Advanced Materials (MIAM) McGill University, 3610 University Street, Montreal, QC, Canada H3A 0C5. milan.maric@mcgill.ca.

Soft Matter
|March 30, 2017
PubMed
Summary

Gradient copolymers (GCPs) with diffuse interfaces show altered self-assembly. Interface diffusion impacts domain spacing and order, with highly diffuse interfaces hindering self-assembly due to reduced interaction parameters.

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