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Frequency comb assisted two-photon vibrational spectroscopy.

Juho Karhu, Markku Vainio, Markus Metsälä

    Optics Express
    |April 7, 2017
    PubMed
    Summary
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    We developed a high-resolution spectroscopy setup using stabilized optical frequency combs. This system achieved sub-Doppler resolution for a two-photon transition in acetylene, demonstrating its high sensitivity and precision.

    Area of Science:

    • Spectroscopy
    • Quantum Optics
    • Molecular Spectroscopy

    Background:

    • High-resolution spectroscopy is crucial for understanding molecular properties.
    • Optical frequency combs offer unprecedented precision for laser stabilization.
    • Two-photon spectroscopy enables probing of specific molecular transitions.

    Purpose of the Study:

    • To report a novel setup for high-resolution two-photon spectroscopy.
    • To demonstrate the capability of the setup for precise molecular measurements.
    • To achieve sub-Doppler resolution and high signal-to-noise ratio.

    Main Methods:

    • Utilizing a mid-infrared continuous wave optical parametric oscillator (CW-OPO) and a near-infrared diode laser.
    • Locking both lasers to fully stabilized optical frequency combs.

    Related Experiment Videos

  • Employing an optical phase-locked loop for diode laser stabilization and frequency locking for mid-infrared comb stabilization.
  • Main Results:

    • Successfully measured a double resonant two-photon transition to a symmetric vibrational state of acetylene.
    • Achieved sub-Doppler resolution, significantly enhancing spectral detail.
    • Obtained a high signal-to-noise ratio, indicating the setup's sensitivity.

    Conclusions:

    • The developed spectroscopy setup provides high-resolution measurements with excellent precision.
    • The system is capable of detailed molecular state analysis.
    • This technique advances the study of molecular vibrations and spectroscopy.