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Published on: July 18, 2025
Monolithic porous magnesium silicide
N Hayati-Roodbari1, R J F Berger, J Bernardi
1Chemistry and Physics of Materials, University of Salzburg, 5020 Salzburg, Austria. michael.elsaesser@sbg.ac.at.
Abstract:
Macroporous magnesium silicide monoliths were successfully prepared by a two-step synthesis procedure. The reaction of gaseous magnesium vapor with macro-/mesoporous silicon, which was generated from hierarchically organized meso-/macroporous silica by a magnesiothermic reduction reaction, resulted in monolithic magnesium silicide with a cellular, open macroporous structure. By adjusting the reaction conditions, such as experimental set-up, temperature and time, challenges namely loss of porosity or phase purity of Mg2Si were addressed and monolithic magnesium silicide with a cellular network builtup was obtained.

