Sulfide emissions in sewer networks: focus on liquid to gas mass transfer coefficient

H₂S emission dynamics in sewers are conditioned by the mass transfer coefficient at the interface. This work aims at measuring the variation of the mass transfer coefficient with the hydraulic characteristics, with the objective of estimating H₂S emission in gravity pipes, and collecting data to establish models independent of the system geometry. The ratio between the H₂S and O₂ mass transfer coefficient was assessed in an 8 L mixed reactor under different experimental conditions. Then, oxygen mass transfer measurements were performed in a 10 m long gravity pipe. The following ranges of experimental conditions were investigated: velocity flow [0-0.61 m.s^-1], Reynolds number [0-23,333]. The hydrodynamic parameters at the liquid/gas interface were calculated by computational fluid dynamics (CFD). In the laboratory-scale reactor, the O₂ mass transfer coefficient was found to depend on the stirring rate (rph) as follows: K_L,O = 0.016 + 0.025 N^3.85. A K_L,H/K_L,O ratio of 0.64 ± 0.24 was found, in accordance with previously published data. CFD results helped in refining this correlation: the mass transfer coefficient depends on the local interface velocity u_i (m.h^-1): K_L,O = 0.016 + 1.02 × 10^-5 u_i^3.85 In the gravity pipe device, K_L,O also exponentially increased with the mean flow velocity. These trends were found to be consistent with the increasing level of turbulence.