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    A new analytical effective medium approximation (EMA) models finite-sized, interacting inclusions in Rayleigh scattering. This model accurately predicts effective parameters for various inclusion sizes and densities, outperforming existing methods.

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    Area of Science:

    • Physics
    • Materials Science
    • Optics

    Background:

    • Modeling electromagnetic wave interaction with composite materials is crucial.
    • Existing effective medium approximations (EMAs) have limitations with finite-sized and interacting inclusions.
    • The Rayleigh scattering regime is important for understanding light interaction with small particles.

    Purpose of the Study:

    • To develop a simple analytical effective medium approximation (EMA) for systems with finite-sized and interacting inclusions.
    • To accurately predict the effective parameters of composite materials in the Rayleigh scattering regime.
    • To compare the developed EMA with experimental results and existing models.

    Main Methods:

    • Calculated individual inclusion polarizability using Mie theory.
    • Expanded Mie coefficients into sixth-order polynomials for Rayleigh regime accuracy.
    • Formulated net polarizability to derive effective medium parameters.
    • Validated the model against experimental data and other EMAs.

    Main Results:

    • The developed analytical EMA accurately accounts for finite-sized and interacting inclusions.
    • The model shows high accuracy in the Rayleigh scattering regime.
    • The proposed analytical formula outperforms existing EMAs for large inclusion sizes, high filling factors, and high relative refractive indices.

    Conclusions:

    • The presented simple analytical EMA provides a robust method for modeling composite materials with complex inclusions.
    • This approach offers improved accuracy over existing EMAs, particularly under challenging conditions.
    • The findings are significant for applications involving light scattering in composite media.