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Updated: Mar 3, 2026

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Published on: February 7, 2017
Helical Folding of Meta-Connected Aromatic Oligoureas
Ting Hu1, Alan L Connor2, Daniel P Miller2
1College of Chemistry, Beijing Normal University , 100875 Beijing, China.
Abstract:
Aromatic oligoureas composed of meta-linked residues bearing phenolic ether side chains are synthesized. The basic N,N'-diarylurea units adopt a trans,trans intramolecularly H-bonded conformation that is further strengthened by additional intermolecular H-bonding. Such basic units, in combination with meta-linked benzene residues, result in stably folded helical oligoureas in the highly polar DMF with up to four turns and with a small cylindrical inner pore that would be difficult to acquire.
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