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Updated: Mar 2, 2026

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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B(C6F5)3-Catalyzed Michael Reactions: Aromatic C-H as Nucleophiles

Wu Li1, Thomas Werner1

  • 1Leibniz Institute for Catalysis at the University of Rostock , Albert-Einstein-Straße 29a, 18059 Rostock, Germany.

Organic Letters
|May 12, 2017
PubMed
Summary

This study introduces a new Michael reaction using aromatic C(sp2)-H nucleophiles for carbon-carbon bond formation. The Lewis acid catalyzed reaction offers a mild and regioselective method for synthesizing complex molecules.

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