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A Direct, Regioselective and Atom-Economical Synthesis of 3-Aroyl-N-hydroxy-5-nitroindoles by Cycloaddition of 4-Nitronitrosobenzene with Alkynones
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A Direct, Regioselective and Atom-Economical Synthesis of 3-Aroyl-N-hydroxy-5-nitroindoles by Cycloaddition of 4-Nitronitrosobenzene with Alkynones

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Ortho-Nitro Effect on the Diastereoselective Control in Sulfa-Staudinger and Staudinger Cycloadditions

Zhanhui Yang1, Hassane Abdellaoui2, Wei He3

  • 1State Key Laboratory of Chemical Resource Engineering, Department of Organic Chemistry, Faculty of Science, Beijing University of Chemical Technology, Beijing 100029, China. zhyang_2008a@163.com.

Molecules (Basel, Switzerland)
|May 13, 2017
PubMed

Keywords:
Staudinger cycloadditiondiastereoselectivityinductive effectnitro effectstereochemistrysulfa-Staudinger cycloaddition

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