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Mechanically-Controlled Reversible Spin Crossover of Single Fe-Porphyrin Molecules
Guowen Kuang1, Qiushi Zhang1, Tao Lin1
1Department of Physics, The Hong Kong University of Science and Technology , Hong Kong, China.
Abstract:
Spin-crossover (SCO) molecules are thought to be ideal systems for molecular spintronics when SCO can be precisely controlled at the single-molecule level. This is demonstrated here in the single-molecule junctions of Fe-porphyrin formed in a scanning tunneling microscope. Experimentally, we find that the junctions feature a zero-bias resonance in molecular conductance associated with the Fe spin center. When mechanically stretching or squeezing the junctions by adjusting the tip height, the line shape of the zero-bias resonance varies reversibly. First-principles calculations reveal that widening the junction gap by 2 Å transforms the macrocyclic core hosting the Fe center from a saddle to a planar conformation. This conformational change shortens the Fe-N bonds by 3%, which changes the Fe spin state from S = 2 to S = 1.
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