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Updated: Jun 11, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks

Synthesis and Characterization of Functionalized Metal-organic Frameworks

Published on: September 5, 2014

Visible Light Induced Organic Transformations Using Metal-Organic-Frameworks (MOFs).

Xiaoyu Deng¹, Zhaohui Li¹, Hermenegildo García²

¹Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350002, P. R. China.

Chemistry (Weinheim an Der Bergstrasse, Germany)

|May 16, 2017

Summary

Metal-organic frameworks (MOFs) are emerging as powerful photocatalysts for light-induced organic synthesis. This review highlights their diverse applications in oxidation, hydroxylation, C-H activation, and polymerization, paving the way for renewable energy processes.

Keywords:

light induced reactions metal-organic frameworks (MOFs)multi-functional compounds organic transformations

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Area of Science:

Materials Science
Organic Chemistry
Photocatalysis

Background:

Metal-organic frameworks (MOFs) are hybrid materials with unique porous structures.
MOFs are gaining attention as photoactive materials for organic synthesis.
Renewable energy-driven processes are increasingly important in chemical transformations.

Purpose of the Study:

To review recent applications of MOFs as photocatalysts in light-induced organic transformations.
To provide a starting point for researchers entering the field of MOF photocatalysis.
To stimulate research in designing MOF materials for enhanced photocatalysis.

Main Methods:

Summarizing recent literature on MOF applications in photocatalysis.
Describing MOFs with photoactive inorganic nodes and ligands.
Discussing MOFs as multifunctional catalysts merging metal/ligand/guest catalysis.

Main Results:

MOFs catalyze various organic transformations: oxidation, hydroxylation, C-H activation, and atom-transfer radical polymerization (ATRP).
Photoactivity stems from inorganic nodes and organic ligands within MOFs.
Multifunctional MOFs integrate photocatalysis with other catalytic mechanisms.

Conclusions:

MOFs show significant potential as photocatalysts for sustainable organic synthesis.
Further research is needed to overcome limitations and rationally design MOFs for visible-light catalysis.
This field offers opportunities for developing novel light-induced organic transformations.