Application of Cu₃InSnSe₅ Heteronanostructures as Counter Electrodes for Dye-Sensitized Solar Cells

In this research, we reported the synthesis of quaternary Cu₃InSnSe₅ nanoparticles with uniform size distribution and morphology for the first time through delicate controls over the chemical reaction kinetics. On the basis of the preparation strategy of Cu₃InSnSe₅ nanoparticles, Pt-Cu₃InSnSe₅ and Au-Cu₃InSnSe₅ heteronanostructures were designed and yielded using a simple and efficient seed growth method. These two heteronanostructures remained monodispersed without presence of any Cu₃InSnSe₅ nanocrystal impurities. To explore their application potentials for dye-sensitized solar cells, counter electrodes consisting of individual Cu₃InSnSe₅, Pt-Cu₃InSnSe₅, or Au-Cu₃InSnSe₅ constituents were fabricated. Current density-voltage (J-V) characteristics evaluation reveals that Cu₃InSnSe₅ nanoparticles, Pt-Cu₃InSnSe₅ and Au-Cu₃InSnSe₅ heterostructured nanoparticles display a comparative power conversion efficiency (PCE) of 5.8%, 7.6%, and 6.5% to that of a Pt-based counter electrode (7.9%), respectively. As such, we believe that the reported preparation strategy could provide new insights to the design and manufacture of counter electrode materials with controlled structure, morphology, and optimized power conversion efficiency for dye-sensitized solar cells.