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Updated: Mar 2, 2026

Preparation of Expanded Chitin Foams and their Use in the Removal of Aqueous Copper
Published on: February 27, 2021
The effect of pH on the bonding of Cu2+ and chitosan-montmorillonite composite
Chao Hu1, Guoyuan Li2, Yiyu Wang2
1College of Resources and Environment, Huazhong Agricultural University, Wuhan 430070, China; Department of Life Sciences and Technologies, Hubei Engineering University, Xiaogan 432000, China.
Abstract:
Based on the contradict statements on the mechanisms of the bonding between metal ions and chitosan based adsorbent, this paper present studies on the Cu2+ adsorption by the chitosan-montmorillonite composite. The in situ attenuated total reflectance Fourier transform infrared spectroscopy and two dimensional correlation analysis were used to record the spectra during the adsorption and the pH perturbation, and analyze the interaction sequence of the groups related to the adsorption, respectively. The results showed that the bonding with -NH3+ might attribute the adsorption capacity greater than that with hydroxyl. The hydroxyl of chitosan (or composite) take part in the Cu2+ adsorption at pH 3.0-5.0 and were more active at lower pH. The amino replaced hydroxyl as the bonding sites with the change of -NH3+ to -NH2 by proton exchange when pH was near 5.0.
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