A functional applied material on recognition of metal ion zinc based on the double azine compound
Taibao Wei1,2, Guoyan Liang1,2, Xiaopeng Chen1,2
1Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education, Gansu 730070, PR China.
Abstract:
A colorimetric and fluorescent probe L has been designed and synthesized, which bearing the double azine moiety and showing a detection limit of 2.725 × 10-7 M towards Zn2+. Based on the basic recognition mechanism of ESIPT and CHEF effect, the L has high selectivity and sensitivity to only Zn2+ (not Fe3+, Hg2+, Ag+, Ca2+, Co2+, Ni2+, Cd2+, Pb2+, Cr3+, and Mg2+) within the physiological pH range (pH = 7.0-8.4) and showed a fluorescence switch. Moreover, this detection progress occured in the DMSO/H2O ∼ HEPES buffer (80/20, v/v; pH 7.23) solution which can conveniently used on test strip.
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