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Infrared Laser Ablation with Vacuum Capture for Fingermark Sampling.

Fabrizio Donnarumma1, Eden E Camp1, Fan Cao1

  • 1Department of Chemistry, Louisiana State University, Baton Rouge, LA, 70803, USA.

Journal of the American Society for Mass Spectrometry
|May 24, 2017
PubMed
Summary

This study introduces infrared laser ablation with vacuum capture for forensic analysis of fingermarks. This technique successfully detected trace evidence like caffeine, lubricants, peptides, and explosives from various surfaces.

Keywords:
FingermarksForensicsGC-MSLaser ablationMALDIVacuum capture

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Area of Science:

  • Forensic Science
  • Analytical Chemistry
  • Surface Science

Background:

  • Effective collection of trace evidence from fingermarks is crucial in forensic investigations.
  • Surface characteristics like porosity and roughness can challenge traditional trace evidence collection methods.

Purpose of the Study:

  • To develop and demonstrate a novel method for collecting fingermark material from diverse surfaces.
  • To validate the applicability of infrared laser ablation coupled with vacuum capture for forensic trace analysis.

Main Methods:

  • Infrared laser ablation (3 μm) in reflection mode was used to ablate fingermark material.
  • Vacuum capture with a filter was employed to collect the ablated ejecta.
  • Analysis was performed using Matrix Assisted Laser Desorption Ionization (MALDI) and Gas Chromatography Mass Spectrometry (GC-MS).

Main Results:

  • Successful ablation and capture of fingermark standards were demonstrated on glass, plastic, aluminum, and cardboard.
  • Trace amounts of caffeine (as low as 1 ng) were detected using MALDI.
  • Condom lubricants, antibacterial peptides, and explosives were successfully identified from fingermarks and direct deposition samples.

Conclusions:

  • Infrared laser ablation coupled with vacuum capture is a viable technique for forensic trace evidence collection.
  • This method shows promise for the sensitive detection of diverse chemical compounds from fingermarks on various substrates.