Quantification of nitrous oxide in wastewater based on salt-induced stripping

Monitoring nitrous oxide (N₂O) emissions from wastewater treatment plants has attracted much attention in recent years demanding accurate and rapid quantification methods. In the present study a salt-assisted methodology is proposed by which N₂O is chemically stripped out from wastewater and quantified by gas chromatography (GC-TCD) subsequently. Eight different inorganic salts have been evaluated for this purpose, likewise the application of ultrasound. By addition of sodium bromide (NaBr) the best recovery rate of about 98% (=1.14±0.05kg·m^-3) N₂O from a saturated stock solution (1.16kg·m^-3, 295.85K and 1atm) was achieved. The application of ultrasound led to considerable smaller N₂O recoveries of 37% (=0.43±0.01kg·m^-3) after a 60min treatment. Practical applicability of the method has been demonstrated by applying NaBr to grab samples from a municipal wastewater treatment plant. The highest N₂O concentration was found in the secondary clarifier with 10.99±0.20g·m^-3. Besides, N₂O could be quantified in the activated sludge process with up to 9.87±0.50g·m^-3 yielding 7.75gN₂O·PE^-1·a^-1 specifically for the investigated wastewater treatment plant. Hence, the proposed method proved suitable as a routine quantification method for N₂O.