Enhanced Superhydrophobic Performance of BN-MoS₂ Heterostructure Prepared via a Rapid, One-Pot Supercritical Fluid...

Fabrication of highly crystalline BN-MoS₂ heterostructure with >95% yield was demonstrated using one-pot supercritical fluid processing within 30 min. The existence of 20-50 layers of BN-MoS₂ in the prepared heterostructure was confirmed by AFM analysis. The HR-TEM imaging and mapping analysis revealed the well-melded BN and MoS₂ nanosheets in the heterostructure. The drastic reduction in XRD line intensities corresponding to the (002) plane and broadening of the peaks for the BN system over MoS₂ indicated the effective exfoliation and lateral size reduction in BN nanosheets during SCF processing. Also, the exfoliated MoS₂ nanosheets are preferentially exposed rather than BN nanosheets; consequently, the MoS₂ nanosheets sturdily covered BN nanosheets in the heterostructure. The exfoliated BN and MoS₂ nanosheets with nanoscale roughness make the surface highly hydrophobic in nature. As a result, the BN-MoS₂ heterostructure showed superior superhydrophobic performance with high water contact angle of 165.9°, which is much higher than the value reported in the literature.