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Updated: Mar 1, 2026

Development of Sulfidogenic Sludge from Marine Sediments and Trichloroethylene Reduction in an Upflow Anaerobic Sludge Blanket Reactor
Published on: October 15, 2015
Activation of peroxymonosulfate by nitrogen-functionalized sludge carbon for efficient degradation of organic
Hongwei Sun1, Xingxing Peng2, Shuping Zhang3
1School of Environmental Science and Engineering, Sun Yat-sen University, Guangzhou 510006, PR China; School of Urban Construction, Zhongkai University of Agriculture and Engineering, Guangzhou 510220, PR China.
Abstract:
Nitrogen-functionalized sludge carbon (NSC) was prepared by urea-mediated pyrolysis of sewage sludge (SS) and was introduced, for the first time, as a potential metal-free catalyst to activate peroxymonosulfate (PMS) for oxidative removal of organic pollutants in water. The nitrogen functionalization of NSC catalysts significantly affected the chemical micro-environments as well as microstructures (morphology and porosity), improving the PMS activation activity towards removing various pollutants, e.g., acid orange 7, phenol and rhodamine B. On the basis of quenching studies and electron paramagnetic resonance, the formed dominant reactive oxidative species (ROS) in the NSC/PMS system was clarified to be nonradical singlet oxygen, in addition to the typical radical ROSs, sulfate and hydroxyl radicals. The incorporated pyridine N, graphite N and pristine CO in the NSC framework promoted the generation of ROS. This study provided new insights into environmentally friendly resourcing SS and exploiting novel cost-effective metal-free catalyst for PMS activation.
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