Potential-Induced Aggregation of Anionic Porphyrins at Liquid|Liquid Interfaces

Sho Yamamoto1, Hirohisa Nagatani1, Hisanori Imura1

  • 1Division of Material Chemistry, Graduate School of Natural Science and Technology, and ‡Faculty of Chemistry, Institute of Science and Engineering, Kanazawa University , Kakuma, Kanazawa 920-1192, Japan.

Summary

Anionic porphyrins like H4TPPS2- and H2PP2- aggregate at liquid interfaces, controlled by applied potentials. This potential-induced aggregation is reversible and can be modulated by factors like phospholipid adsorption.

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